I think that Captain America has a certain respect for the kid, however, there is still the fact that he is dated and he really doesn't know how teenager's act. That could be something that Bendis could work with which would prove to be quite comical.
Iron Man is a comedian in his own way and Spider-Man could play off of his arrogant sides, which would definitely make some interesting moments.
Wasp will be the person that Spider-Man will most likely admire out of all of them. Not only is she a hero, but she is a scientist. She is the person that is most like Peter, really. I think that would be interesting.
Spider-Man will definitely have a problem with Thor. The fact that he's so weird will give PEter ideas and stuff. May be funny, may actually spook people out.